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dc.contributor.authorÁlvarez Álvarez, María Salomé 
dc.contributor.authorLongo González, María Asunción 
dc.contributor.authorDeive Herva, Francisco Javier 
dc.contributor.authorRodríguez Rodríguez, Ana María 
dc.date.accessioned2022-01-12T11:35:46Z
dc.date.available2022-01-12T11:35:46Z
dc.date.issued2021-10-15
dc.identifier.citationJournal of Molecular Liquids, 340, 117230 (2021)spa
dc.identifier.issn01677322
dc.identifier.urihttp://hdl.handle.net/11093/2970
dc.descriptionFinanciado para publicación en acceso aberto: Universidade de Vigo/CISUG
dc.description.abstractThe main objective of the present work was to synthesize and characterize three novel lipase-friendly deep eutectic solvents (DESs) using cholinium dihydrogen phosphate (N1112OHDHP) as hydrogen bond acceptor and ethylene glycol (EG) and/or glycerol (GL) as hydrogen bond donors in the following proportions: N1112OHDHP:EG (molar ratio 1:2), N1112OHDHP:GL (molar ratio 1:2) and N1112OHDHP:EG:GL (molar ratio 1:1:1). FTIR, 1H NMR, TGA and DSC were employed to shed light on their distinctive structural characteristics. Density, refractive index and dynamic viscosity were also measured at different temperatures, and the experimental data were correlated with several well-known equations. Finally, the suitability of the newly synthesized DESs to be employed in biocatalytic reactions was demonstrated by analysing the activity of a commercial enzyme (Candida antarctica lipase B) after being in contact with them.en
dc.description.sponsorshipAgencia Estatal de Investigación | Ref. RTI2018-094702-B-I00spa
dc.description.sponsorshipXunta de Galicia | Ref. ED481D-2019/017spa
dc.language.isoengen
dc.publisherJournal of Molecular Liquidsspa
dc.relationinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-094702-B-I00/ES/LA BIOECONOMIA VERDE COMO INSPIRACION PARA EL DISEÑO DE UN PROCESO DE PRODUCCION DE BIODIESEL SIN GLICEROL BASADO EN BIOCATALIZADORES EXTREMOS Y DISOLVENTES DE DISEÑO
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 International
dc.rights.urihttps://creativecommons.org/licenses/by-nc-nd/4.0/
dc.titleSynthesis and characterization of a lipase-friendly DES based on cholinium dihydrogen phosphateen
dc.typearticlespa
dc.rights.accessRightsopenAccessspa
dc.identifier.doi10.1016/j.molliq.2021.117230
dc.identifier.editorhttps://linkinghub.elsevier.com/retrieve/pii/S0167732221019541spa
dc.publisher.departamentoEnxeñaría químicaspa
dc.publisher.grupoinvestigacionEnxeñería Química 3spa
dc.publisher.grupoinvestigacionProcesos de Separaciónspa
dc.subject.unesco2301.18 Métodos Termoanalíticosspa
dc.subject.unesco2301.09 Espectroscopia de Resonancia Magnéticaspa
dc.subject.unesco2302.09 Enzimologíaspa
dc.date.updated2021-12-23T12:20:17Z


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