Formation of Indanone from an Iridanaphthalene Complex
DATE:
2013-07-30
UNIVERSAL IDENTIFIER: http://hdl.handle.net/11093/7410
EDITED VERSION: https://pubs.acs.org/doi/10.1021/om400702b
UNESCO SUBJECT: 2303.21 Compuestos Organometálicos
DOCUMENT TYPE: article
ABSTRACT
The first example of evolution of an iridanaphthalene into an indanone through an intermediate indenyl is reported, serving as a good example of starting material to obtain indanones. Two new iridanaphthalenes are obtained by intramolecular C–H activation of a phenyl ring of a carbene ligand in [IrCp*{C(OMe)CHCPh2}(L)]PF6 (L = PPh2Me, PMe3) complexes. It is demonstrated that these iridanaphthalene complexes can undergo a thermal reaction to give indenyl complexes and 3-phenylindanone.
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