RT Journal Article
T1 A chiral molecular cage comprising diethynylallenes and N‐heterotriangulenes for enantioselective recognition
A1 Miguez Lago, Sandra
A1 Gliemann, Bettina D.
A1 Kivala, Milan
A1 Cid Fernandez, María Magdalena
K1 2306 Química Orgánica
AB Chirality, a characteristic tool of molecular recognition in nature, is often a complement of redox active systems. Scientists, in their eagerness to mimic such sophistication, have designed numerous chiral systems based on molecular entities with cavities, such as macrocycles and cages. In an attempt to combine chirality and redox-active species, in this contribution we report the synthesis and detailed characterization of a chiral shape-persistent molecular cage based on the combination of enantiopure diethynylallenes and electron-rich bridged triarylamines, also known as N-heterotriangulenes. Its ability for chiral recognition in solution was revealed through UV/vis titrations with enantiopure helicenes.
PB Chemistry - A European Journal
SN 09476539
YR 2021
FD 2021-09-20
LK http://hdl.handle.net/11093/3819
UL http://hdl.handle.net/11093/3819
LA eng
NO Chemistry - A European Journal, 27(53): 13352-13357 (2021)
NO Financiado para publicación en acceso aberto: Universidade de Vigo/CISUG
NO Agencia Estatal de Investigación | Ref. CTQ2017-85919-R
DS Investigo
RD 18-sep-2024