RT Journal Article
T1 Tris‐isocyanide copper(I) complex enabling copper azide‐alkyne cycloaddition in neat conditions
A1 Ferraro, Valentina
A1 Sole, Roberto
A1 Bortoluzzi, Marco
A1 Beghetto, Valentina
A1 Castro Fojo, Jesús Antonio
K1 2303 Química Inorgánica
AB The three‐coordinated homoleptic Cu(I) complex with 2,6‐dimethylphenyl isocyanide in the coordination sphere was easily synthesized and isolated as tetrafluoroborate salt. The structure of the compound was determined by single‐crystal X‐ray diffraction. The complex is highly stable, active and selective toward the copper‐catalyzed azide‐alkyne cycloaddition, working in neat conditions and in the absence of bases at room temperature. Substrate scope was assessed by testing several different alkynes and azides. In most cases the corresponding 1,4‐disubstituted‐1,2,3‐triazoles were isolated in high yields.
PB Applied Organometallic Chemistry
SN 02682605
YR 2021
FD 2021-08-11
LK http://hdl.handle.net/11093/5322
UL http://hdl.handle.net/11093/5322
LA eng
NO Applied Organometallic Chemistry, 35(11): 6401 (2021)
NO Università Ca' Foscari di Venezia  | Ref. Bando Spin 2018, D. R. 1065/2018 prot. 67416
DS Investigo
RD 15-sep-2024